Effects of perfluoroalkyl substances (PFAS) on antioxidant depletion from a high-density polyethylene geomembrane.

To safely contain Per-and Polyfluoroalkyl substances (PFAS) in municipal solid waste landfills and contaminated soil monofills, it is necessary to understand how these substances interact with components of engineered systems designed to contain them. This paper examines the interaction between one of the most critical components of the system: a high-density polyethylene (HDPE) geomembrane. The same geomembrane is immersed in PFAS solution and synthetic municipal solid waste leachate containing PFAS for 2.5 years, and the effects of PFAS on antioxidant depletion time is examined. The geomembrane is incubated in ovens at 85-40 °C to obtain data for Arrhenius predictions at typical landfill temperatures. When exposed to PFAS solution alone, the antioxidant depletion times are smaller than when the same geomembrane is immersed in synthetic municipal solid waste leachate alone. The combination of the two has a synergistic effect which leads to an even greater reduction in antioxidant depletion time for this geomembrane, with results showing a 68% decrease in predicted antioxidant depletion time at a typical landfill temperature of 35 °C when PFAS is present in leachate. This study highlights the need to consider the potential impact of PFAS on the service life of geomembranes used to contain them.

PFOA and PFOS diffusion through LLDPE and LLDPE coextruded with EVOH at 22 °C, 35 °C, and 50 °C.

Diffusion of perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS) through 0.1 mm and 0.75 mm LLDPE and 0.1 mm and 0.75 mm LLDPE coextruded with ethyl vinyl alcohol (denoted as CoEx) at room temperature (23 °C), 35 °C, and 50 °C is examined. These tests had negligible source depletion throughout the monitoring period, indicating limited contaminant partitioning and diffusion through the LLDPE. At 483 days, 23 °C receptor PFOA and PFOS concentrations, cr, were <8 µg/L (cr/co < 3.2 × 10-4) for all tests, and at 399 days elevated temperature receptor concentrations were < 0.4 µg/L (cr/co < 1.6 × 10-5) at 35 °C and <0.5 µg/L (cr/co < 2.0 × 10-5) at 50 °C for both PFOA and PFOS. LLDPE partitioning coefficient, Sgf was 0.9-1.4 (PFOA) and 2.8-5.3 (PFOS) based on sorption tests at 23 °C. Based on the best estimates of permeation coefficient, PgCoEx, for CoEx was consistently lower than PgLLDPE. For PFOA, CoEx had PgCoEx < 0.26 × 10-16 m2/s at 23 °C, <11 × 10-16 m2/s (35 °C), and < 10 × 10-16 m2/s (50 °C) while LLDPE had PgLLDPE < 3.1 × 10-16 m2/s (23 °C), <13 × 10-16 m2/s (35 °C), and <19 × 10-16 m2/s (50 °C). For PFOS, CoEx and LLDPE had PgCoEx < 0.55 × 10-16 m2/s and PgLLDPE < 3.2 × 10-16 m2/s (23 °C), PgCoEx < 8.3 × 10-16 m2/s and PgLLDPE < 40 × 10-16 m2/s (35 °C), and PgCoEx < 8.2 × 10-16 m2/s and PgLLDPE < 52 × 10-16 m2/s (50 °C). These values are preliminary and may change (e.g., decrease) as more data comes available over time. The Pg values deduced for PFOA and PFOS are remarkably lower than those reported for other contaminants of concern, excepting BPA, which exhibits similar behaviour.

Control and estimation of maximum gas pressure below landfill cover with horizontal gas wells: Analytical study.

Horizontal spacing of horizontal extraction gas wells can be designed to achieve a 90% pumping rate of the total generated landfill gas (LFG) from given waste properties (viz: gas permeability, landfill gas generation and non-homogeneity with depth), cover characteristics and vacuum pressure. However, cover characteristics and vacuum pressure are also important design parameters and different combinations of them result in different distributions of gas pressure in the waste, some of which would induce problematic air intrusion while others might pose threat to cover stability. This paper uses the maximum gas pressure directly below cover to distinguish these combinations, and provides the first study of the effects of the above parameters on potential outcomes. The ability of the overlying cover to resist LFG emission from the landfilled waste is suggested not to exceed a critical value, otherwise the maximum gas pressure below it would become at least 1 kPa larger than atmospheric pressure. A design formula for this critical value is proposed with respect to typical values of waste properties, vacuum pressure and the buried depth of horizontal wells in wide ranges. Together with consideration of recovery efficiency, the proposed method can be used to design a horizontal extraction gas collection system and a cover system in better working condition, and to evaluate the maximum gas pressure below cover. These applications are illustrated by a worked example.

Representative stress crack resistance of polyolefin geomembranes used in waste management.

The decrease in stress crack resistance (SCR) of geomembranes (GMBs) due to physical ageing is examined. It is shown that the SCR of a 1.5 mm high density polyethylene (HDPE) GMB immersed in municipal solid waste (MSW) leachate, deionized (DI) water, and air experienced a decrease to an equilibrium value, denoted herein as SCRm, in a few months and then did not change for the remainder of a 116-month test. The same GMB was also immersed in basic mining pregnant leach solution (PLS) and brine and a similar decrease in SCR to SCRm was observed in the first three months. For this GMB, SCRm was about 50% of the initial SCR value (i.e., SCRm ∼ 0.5·SCRo) for all incubation fluids examined. It is then shown that this behaviour is not unique. Seven other high density polyethylene (HDPE) and one blended polyolefin (BPO) GMBs are shown to experience a decrease in SCR to 0.17·SCRo ≤ SCRm ≤ 0.56·SCRo without any evidence of oxidative degradation. The magnitude of SCRm is shown to be product specific. In contrast, the one linear low density polyethylene (LLDPE) examined exhibited no such physical ageing. The implications for designing with GMBs are discussed.

Design of horizontal landfill gas collection wells in non-homogeneous landfills.

Considering exponential decreases in gas permeability and gas generation of waste with depth, a two-dimensional analytical model is developed to describe the landfill gas (LFG) recovery using horizontal wells. This model is used to simulate more than 680,000 scenarios involving typical values of waste properties, cover characteristics and design parameters for horizontal wells (seven variables in total). The coupled effect of these seven variables on air intrusion and the gas recovery efficiency of horizontal wells are investigated. It is shown that all the variables examined, except for the two variables defining waste non-homogeneity, could be integrated into three dimensionless variables. The horizontal spacing and buried depth of horizontal wells are examined as a function of cover characteristics, waste properties, and vacuum pressure to allow the development of a generalized design method for horizontal wells. An upper limit of horizontal well spacing is defined (for an 85% recovery rate) and a simple formula is provided which can be used to estimate the corresponding level of air intrusion. The upper limit spacing is shown to be affected by the non-homogeneity in gas permeability of waste, cover characteristics, and buried well depth. Using a worked example, the proposed method is shown to be capable of estimating air intrusion into existing horizontal gas collection wells and to optimize the design of horizontal wells considering waste non-homogeneity.

Recovery response of vertical gas wells in non-homogeneous landfills.

A two-dimensional axisymmetric and normalized analytical model for landfill gas (LFG) migration around a vertical well is developed. The vertical gas permeability and LFG generation rate of waste are assumed to be subject to exponential decreases with depth. Using a general analytical solution, over 500,000 scenarios involving a combination of typical control variables (viz: cover properties, waste properties, vacuum pressure, well radius and spacing) are modelled. A quantitative analysis of the coupled effects of these control variables on LFG recovery rate indicates that the recovery response could be captured by: (a) three dimensionless variables (denoted as cover resistance, pump capacity, and well spacing parameters), and (b) two constants defining the decreases in gas permeability and LFG generation of waste with depth. For example, if the LFG generation rate of the waste at the top is doubled, a two times increase in the vacuum pressure with other parameters being equal would give a same gas recovery rate, as well as simultaneously doubling the thickness and gas permeability of the cover. The recovery efficiency of a vertical well with a low permeability cover is examined as a function of cover resistance and pump capacity, and design charts are presented that may be used to optimize gas recovery by adjusting cover properties and vacuum pressure. The proposed model makes it possible to consider the waste non-homogeneity in the design process, and the results contribute to a preliminary design of a cover and vertical LFG collection systems.

Design of vertical landfill gas collection wells considering non-homogeneity with depth.

Considering variable gas permeability and gas generation of waste with depth, different combinations of cover properties, vacuum pressure, and horizontal spacing of vertical wells giving rise to a 90% gas recovery rate are identified for typical waste properties. The effects of passive and active gas collection on horizontal well spacing are quantified. The normalized well spacing for 90% recovery is examined as a function of the cover resistance and the vacuum pump capacity. Design charts dependent on changes in gas permeability and gas generation rate with depth are presented to aid in the design of vertical gas wells. It is demonstrated that the non-homogeneity in gas permeability of waste is of great importance. For a conservative design, uncertainty in the non-homogeneity in gas permeability should be overestimated while uncertainty with respect to the non-homogeneity in LFG generation should generally be underestimated. The use of the proposed method for the design of the spacing of vertical gas wells in a situation with waste non-homogeneity is illustrated by a practical example.

Geomembrane applications for controlling diffusive migration of petroleum hydrocarbons in cold region environments.

Laboratory permeation tests examine the migration of aromatic hydrocarbons (benzene, toluene, ethylbenzene and xylenes (BTEX)) at 2, 7 and 14 °C through three different types of geomembrane (high density polyethylene (HDPE), linear low density polyethylene (LLDPE) and polyvinyl chloride (PVC)). Tests on both virgin and exhumed field samples provide permeation parameters (partitioning (Sgf), diffusion (Dg), and permeation (Pg) coefficients) for the three geomembranes. These results are combined with published values for the same geomembranes at 23 °C to establish an Arrhenius relationship that can be used to estimate diffusion parameters at temperatures other than those for which tests were conducted. Tests on an HDPE geomembrane sample exhumed after 3 years from a landfill site in the Canadian Arctic showed no significant difference in diffusion characteristics compared to an otherwise similar unaged and unexposed HDPE geomembrane. Contaminant transport modeling for benzene through HDPE, LLPDE and PVC in a simulated landfill cover show that for the conditions examined the presence of any of the three geomembranes below the 2 m thick soil cover substantially reduced the contaminant flux compared to the soils alone for realistic degrees of saturation in the cover soil. For these same realistic cold climate cases, of the three geomembranes examined, the HDPE geomembrane was the most effective at controlling the contaminant flux out of the landfill. An increase in soil cover and liner temperature by 2 °C (from potential climate change effects) above those currently measured at an Arctic landfill showed an increase in contaminant transport through the cover system for all geomembranes due to the increase surface temperature (especially in the summer months). Modeling of the addition of an extra 0.5 m of soil cover, as a mitigation measure for the effects of climate change, indicates that the main benefit of adding this unsaturated soil was to reduce the geomembrane temperature and that this did reduce the magnitude of the increase in contaminant transport.

Partitioning and diffusion of PBDEs through an HDPE geomembrane.

Polybrominated diphenyl ether (PBDE) has been measured in MSW landfill leachate and its migration through a modern landfill liner has not been investigated previously. To assure environmental protection, it is important to evaluate the efficacy of landfill liners for controlling the release of PBDE to the environment to a negligible level. The partitioning and diffusion of a commercial mixture of PBDEs (DE-71: predominantly containing six congeners) with respect to a high-density polyethylene (HDPE) geomembrane is examined. The results show that the partitioning coefficients of the six congeners in this mixture range from 700,000 to 7,500,000 and the diffusion coefficients range from 1.3 to 6.0×10(-15)m(2)/s depending on the congener. This combination of very high partitioning coefficients and very low diffusion coefficients suggest that a well constructed HDPE geomembrane liner will be an extremely effective barrier for PBDEs with respect to diffusion from a municipal solid waste landfill, as illustrated by an example. The results for pure diffusion scenario showed that the congeners investigated meet the guidelines by at least a factor of three for an effective geomembrane liner where diffusion is the controlling transport mechanism.

Making waste management public (or falling back to sleep).

Human-produced waste is a major environmental concern, with communities considering various waste management practices, such as increased recycling, landfilling, incineration, and waste-to-energy technologies. This article is concerned with how and why publics assemble around waste management issues. In particular, we explore Noortje Marres and Bruno Latour's theory that publics do not exist prior to issues but rather assemble around objects, and through these assemblages, objects become matters of concern that sometimes become political. The article addresses this theory of making things public through a study of a small city in Ontario, Canada, whose landfill is closed and waste diversion options are saturated, and that faces unsustainable costs in shipping its waste to the United States, China, and other regions. The city's officials are undertaking a cost-benefit assessment to determine the efficacy of siting a new landfill or other waste management facility. We are interested in emphasizing the complexity of making (or not making) landfills public, by exploring an object in action, where members of the public may or may not assemble, waste may or may not be made into an issue, and waste is sufficiently routinized that it is not typically transformed from an object to an issue. We hope to demonstrate Latour's third and fifth senses of politics best account for waste management's trajectory as a persistent yet inconsistent matter of public concern.

A framework for a decision support system for municipal solid waste landfill design.

A decision support system (Landfill Advisor or LFAdvisor) was developed to integrate current knowledge of barrier systems into a computer application to assist in landfill design. The program was developed in Visual Basic and includes an integrated database to store information. LFAdvisor presents the choices available for each liner component (e.g. leachate collection system, geomembrane liner, clay liners) and provides advice on their suitability for different situations related to municipal solid waste landfills (e.g. final cover, base liner, lagoon liner). Unique to LFAdvisor, the service life of each engineered component is estimated based on results from the latest research. LFAdvisor considers the interactions between liner components, operating conditions, and the existing site environment. LFAdvisor can be used in the initial stage of design to give designers a good idea of what liner components will likely be required, while alerting them to issues that are likely to arise. A systems approach is taken to landfill design with the ultimate goal of maximising long-term performance and service life.

Clogging of finger drain systems in MSW landfills.

A numerical model 'BioClog' is used to examine clogging of granular drainage material within finger drains at the base of landfills. The reduction in porosity of drainage material is evaluated as the accumulation of clog mass reduces the pore spaces of granular media. The leachate mounding within the landfills caused by the reduction in hydraulic conductivity of finger drain is modeled. The effect of overburden pressure on the engineering properties of waste material and consequent leachate mounding is considered. The calculated rates of leachate mound development for two landfills with finger drain leachate collection are shown to be in encouraging agreement with the observed data at the times when data were available. It is demonstrated that a significant leachate mound can be expected to develop over time when the leachate collection system is comprised of finger drains; however the rate of increase and the magnitude at a given time will depend on a number of factors including the grainsize, thickness and spacing of the finger drains, and the thickness of waste as well as the leachate generation rate.

Design and application of surface PRBs for PCB remediation in the Canadian Arctic.

Over the course of three years, several surface permeable reactive barriers were designed and constructed to deal with leftover site contamination at a site located on the summit of Resolution Island, Nunavut, just southeast of Baffin Island at 61° 35'N and 60° 40'W. The site was part of a North American military defense system established in the 1950s that became heavily contaminated with polychlorinated biphenyls (PCBs) during and subsequent to, its operational years. Each of the three barrier designs has a different configuration, to meet the needs of the targeted remediation area, based on their unique contaminant histories. Modifications were made to the barrier designs based on both field observations and laboratory results. The comparison of field and laboratory results indicated that areas with higher concentrations of PCB contamination behaved differently than areas with lower concentrations of PCB contaminated soil. Previous laboratory studies only partially replicated field observations and results. It had previously been hypothesized that particle retention was the most important factor in trapping and capturing PCBs. However, rinsed filter samples from the field indicated that partitioning of PCBs between contaminated soil and granular activated carbon (GAC) filter particles were occurring at levels of 62 ± 11%, suggesting that sequestration of the PCBs from the environment should be a primary focus of the barrier. This sequestration requires both particle retention (within the granular sorptive filters) as well as maintained contact time between particles for sorption processes to proceed. This mechanism--partitioning of PCB to GAC--was more important in areas with higher PCB concentration. These results suggest that it may be possible to tailor future barrier designs to their unique site histories and locations.

Application of tire chips to reduce the temperature of secondary geomembranes in municipal solid waste landfills.

Heat generated by the biodegradation of waste and other chemical processes in a landfill can potentially affect the long-term performance of landfill liner system, in particular that of a high-density polyethylene geomembrane. In a double liner system, the difference in leachate exposure and temperature might improve the long-term performance of the secondary geomembrane compared to that of the primary geomembrane. However, in some cases, the temperature is likely to be high enough to substantially reduce the service-life of the secondary geomembrane. This study explores the possible effectiveness of using tire chips as thermal insulation between primary and secondary liners to reduce the temperature of secondary geomembranes as compared to traditional soil materials. Heat and contaminant migration analyses are performed for cases with no insulation and for cases in which a layer of soil or tire chips has been used as thermal insulation between the primary and secondary liners. The effect of insulation on prolonging the service-life of a secondary geomembrane and, consequently, on contaminant transport through a liner system is examined for the case of a volatile organic compound (dichloromethane) found in landfill leachate. The study suggests that the use of tire chips warrants consideration, however there are other practical issues that require consideration in the detailed design and construction of landfill liners. Issues such as finite service-life, low working temperature, excessive settlement, ability to generate internal heat, leaching of tire chips and limitations in performing electrical resistivity leak detection tests are identified.

Impact of landfill liner time-temperature history on the service life of HDPE geomembranes.

The observed temperatures in different landfills are used to establish a number of idealized time-temperature histories for geomembrane liners in municipal solid waste (MSW) landfills. These are then used for estimating the service life of different HDPE geomembranes. The predicted antioxidant depletion times (Stage I) are between 7 and 750 years with the large variation depending on the specific HDPE geomembrane product, exposure conditions, and most importantly, the magnitude and duration of the peak liner temperature. The higher end of the range corresponds to data from geomembranes aged in simulated landfill liner tests and a maximum liner temperature of 37 degrees C. The lower end of the range corresponds to a testing condition where geomembranes were immersed in a synthetic leachate and a maximum liner temperature of 60 degrees C. The total service life of the geomembranes was estimated to be between 20 and 3300 years depending on the time-temperature history examined. The range illustrates the important role that time-temperature history could play in terms of geomembrane service life. The need for long-term monitoring of landfill liner temperature and for geomembrane ageing studies that will provide improved data for assessing the likely long-term performance of geomembranes in MSW landfills are highlighted.

Remediation of PCB contaminated soils in the Canadian Arctic: excavation and surface PRB technology.

The site BAF-5 is located on the summit of Resolution Island, Nunavut, just southeast of Baffin Island at 61 degrees 35'N and 60 degrees 40'W. The site was part of a North American military defense system established in the 1950s that became heavily contaminated with PCBs during and subsequent, its operational years. Remediation through excavation of the PCB contaminated soil at Resolution Island began in 1999 and at its completion in 2006 approximately 5 tonnes of pure PCBs in approximately 20,000 m3 of soil were remediated. Remediation strategies were based on both quantity of soil and level of contamination in the soil. Excavation removed 96% of the PCB contaminated soil on site. In 2003, a surface funnel-and-gate permeable reactive barrier was design and constructed to treat the remaining contamination left in rock crevices and inaccessible areas of the site. Excavation had destabilized contaminated soil in the area, enabling contaminant migration through erosion and runoff pathways. The barrier was designed to maximize sedimentation through settling ponds. This bulk removal enabled the treatment of highly contaminated fines and water through a permeable gate. The increased sediment loading during excavation required both modifications to the funnel and a shift to a more permeable, granular system. Granulated activated charcoal was chosen for its ability to both act as a particle retention filter and adsorptive filter. The reduction in mass of PCB and volume of soils trapped by the funnel of the barrier indicate that soils are re-stabilizing. In 2007, nonwoven geotextiles were re-introduced back into the filtration system as fine filtering could be achieved without clogging. Monitoring sites downstream indicate that the barrier system is effective. This paper describes the field progress of PCB remediation at Resolution Island.

Evolution of clog formation with time in columns permeated with synthetic landfill leachate.

Laboratory column tests conducted to gain insight regarding the biological and chemical clogging mechanisms in a porous medium are presented. To seed the porous medium with landfill bacteria, a mixture of Keele Valley Landfill and synthetic leachate permeated through the column under anaerobic conditions for the first 9 days of operation. After this, 100% synthetic leachate was used. The synthetic leachate approximated Keele Valley Landfill leachate in chemical composition but contained negligible suspended solids and bacteria compared with real leachate. The removal of volatile fatty acids (VFAs), primarily acetate, in leachate as it passed through the medium was highly correlated with the precipitation of calcium carbonate (CaCO(3(s))) from solution. The columns experienced a decrease in drainable porosity from an initial value of about 0.38 to less than 0.1 after steady state chemical oxygen demand (COD) removal, resulting in a five-order magnitude decrease in hydraulic conductivity. The decrease in drainable porosity prior to steady state COD removal was primarily due to the growth of a biofilm on the medium surface. After steady state COD removal, calcium precipitation was at least equally responsible for the decrease in drainable porosity as biofilm growth. Clog composition analyses showed that CaCO(3(s)) was the dominant clog constituent and that 99% of the carbonate in the clog material was bound to calcium.

Influence of landfill leachate suspended solids on clog (biorock) formation.

Laboratory column tests were performed to evaluate the role of leachate-suspended-solids in clogging a granular material permeated with Keele Valley Landfill leachate. The development of the clog material was a result of biological, chemical, and physical processes occurring within the column. The increase in volatile solids, which contributed to clog development over time, was primarily due to the retention of volatile suspended solids and growth of a biofilm capable of removing acetate, propionate, and butyrate from the leachate. Acetate fermentation was primarily responsible for precipitation of calcium within the column. The precipitated calcium and retention of inorganic suspended solids contributed to the increase in clog inorganic solids. Over the duration of the experiment, 3.7 times more calcium was precipitated in the column (due to acid fermentation) than was retained with inorganic suspended solids. Clogging resulted in a greater than 60% reduction in drainable porosity and a six-order magnitude decrease in hydraulic conductivity. The potential practical implications with respect to pipe cleaning and leachate recirculation were discussed.

Modelling leachate quality and quantity in municipal solid waste landfills.

The operational phase of landfills may last for 20 years or more. Significant changes in leachate quality and generation rate may occur during this operational period. A mathematical model has been developed to simulate the landfill leachate behaviour and distributions of moisture and leachate constituents through the landfill, taking into consideration the effects of time-dependent landfill development on the hydraulic characteristics of waste and composition of leachate. The model incorporates governing equations that describe processes influencing the leachate production and biochemical processes taking place during the stabilization of wastes, including leachate flow, dissolution, acidogenesis and methanogenesis. To model the hydraulic property changes occurring during the development stage of the landfills, a conceptual modelling approach was proposed. This approach considers the landfill to consist of cells or columns of cells, which are constructed at different times, and considers each cell in the landfill to consist of several layers. Each layer is assumed to be a completely mixed reactor containing uniformly distributed solid waste, moisture, gases and micro-organisms. The use of the proposed conceptual model enables the incorporation of the spatial changes in hydraulic properties of the landfill into the model and also makes it possible to predict the spatial and temporal distributions of moisture and leachate constituents. The model was calibrated and partially verified using leachate data from Keele Valley Landfill in Ontario, Canada and data obtained from the literature. Ranges of values were proposed for model parameters applicable for real landfill conditions.

Predicting biogeochemical calcium precipitation in landfill leachate collection systems.

Clogging of leachate collection systems within municipal solid waste landfills can result in greater potential for contaminants to breach the landfill barrier system. The primary cause of clogging is calcium carbonate (CaCO3(s)) precipitation from leachate and its accumulation within the pore space of the drainage medium. CaCO3(s) precipitation is caused by the anaerobic fermentation of volatile fatty acids (VFAs), which adds carbonate to and raises the pH of the leachate. An important relationship in modeling clogging in leachate collections systems is a yield coefficient that relates microbial fermentation of VFAs to precipitation of calcium carbonate. This paper develops a new, mechanistically based yield coefficient, called the carbonic acid yield coefficient (Y(H)), which relates the carbonic acid (H2CO3) produced from microbial fermentation of acetate, propionate, and butyrate to calcium precipitation. The empirical values of Y(H) were computed from the changes in acetate, propionate, butyrate, and calcium concentrations in leachate as it permeated through gravel-size material. The theoretical and empirical results show that the primary driver of CaCO3(s) precipitation is acetate fermentation. Additionally, other non-calcium cations (e.g., iron and magnesium) precipitated with carbonate (CO3(2-)) when present in the leachate. A common yield between total cations bound to CO3(2-) and H2CO3 produced, called the calcium carbonate yield coefficient (Yc), can reconcile the empirical yield coefficient for synthetic and actual leachates.